Selective electrochemical CO2 conversion with a hybrid polyoxometalate

Satoshi Kuramochi,Jamie M. Cameron,Tomoya Fukui,Kieran D. Jones,Stephen P. Argent,Shinpei Kusaka,Ryo Shiraishi,Yusuke Tamaki,Taiki Yatsu,Takuya Shiga,Osamu Ishitani,Hiroki Oshio,Graham N. Newton

Chemical communications (Cambridge, England)（2023）

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摘要

A multi-component coordination compound, in which ruthenium antenna complexes are connected to a polyoxotungstate core is presented. This hybrid cluster effectively promotes the electrochemical conversion of CO2 to C1 feedstocks, the selectivity of which can be controlled by the acidity of the media.

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