Laser-induced forced evaporative cooling of molecular anions below 4 K

The study of cold and controlled molecular ions has been of key importance for a wide range of applications, such as the production of cold antihydrogen, creation and study of anionic Coulomb crystals and in atmospheric research and astrochemistry. However, the commonly used anion cooling technique via collisions with a buffer gas is limited by the temperature of the used cryogenic cooling medium. Here we demonstrate the forced evaporative cooling of anions via a laser beam with photon energies far above the photodetachment threshold of the anion. We cool an anionic ensemble from an initial temperature of 370(12) K down to 2.2(8) K. This results in a three orders of magnitude increase in the phase-space density of the ions, approaching the near-strong Coulomb coupling regime. We present an analysis of the cooling dynamics through a thermodynamic model that includes the role of intrinsic collisional heating, without any fitting parameters. This technique can be used to cool any anionic species below liquid helium temperature, providing a tool to push the frontiers of anion cooling below state-of-the-art temperature regimes.