Boride-mediated synthesis of a highly active cobalt-based electrocatalyst for alkaline hydrogen evolution reaction
JOURNAL OF MATERIALS CHEMISTRY A(2023)
摘要
The lack of viable means to simultaneously address intrinsic activity, density of active sites and electronic conductivity issues remains a grand challenge restricting the development of earth-abundant electrocatalysts for the alkaline hydrogen evolution reaction (HER). Herein, we report a boride-mediated synthesis method to address these issues. Our study found that a cobalt boride catalyst prepared by the chemical reduction method is actually an amorphous mixture of CoBx, CoO and B-containing impurities. Annealing treatment of this composite initiates a solid reaction between CoBx and CoO, leading to the formation of tiny Co nanoparticles on the surface of amorphous CoO/B2O3 nanosheets. Besides the creation of abundant accessible Co/CoO active sites for the alkaline HER, the annealing treatment can also help increase the specific surface area and improve the electrical conductivity. Benefiting from these favorable attributes, the post-annealed Co/CoO/B2O3/CF catalyst exhibited outstanding HER performance in an alkaline electrolyte. It required overpotentials of 16 and 100 mV to afford 10 and 100 mA cm(-2), respectively, and showed good stability in the long-term operation, outperforming the benchmark Pt/C.
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关键词
hydrogen evolution reaction,electrocatalyst,boride-mediated,cobalt-based
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