A method for calculating catalytic-site amount and judging antagonistic/synergetic effect in multi-metallic catalyst

Applied Surface Science(2023)

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摘要
•A DRIFT strategy was established to evaluate catalytic-site amount.•Mn, Fe, V, and their pairs were loaded on TiO2, and applied SCR.•Turnover frequency per cation was calculated by the established method.•Multi-metal site had a bigger turnover frequency than single-metal site and cluster.•Bimetallic catalyst was more easily agglomerated than mono-metallic catalyst.
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关键词
SCR,DRIFTS,Bimetallic catalyst,Synergetic effect,Antagonistic effect
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