Dual-salt assisted synergistic synthesis of Prussian white cathode towards high-capacity and long cycle potassium ion battery

Prussian blue analogues (PBAs) are considered as superior cathode materials for potassium-ion batteries (PIBs) because of their three-dimensional open framework structure, high stability, and low cost. However, the intrinsic lattice defects and low potassium content typically results in poor rate and cycling performance, thus limited their practical applications. In this work, high-quality K1.64FeFe(CN)6 (PW-HQ) material with less crystalline water (6.21%) and high potassium content (1.64 mol-1) was successfully synthesized by a novel coprecipitation method with potassium citrate (K-CA) and potassium chloride (KCl) addition. Specifically, the electrode delivers a reversible capacity of 113.1 mA h g-1 at the current rate of 50 mA g-1 with-100% coulombic efficiency. Besides, the electrode retained 90% reversible capac-ity at 500 mA g-1 current density after 1000 cycles, indicating only 0.01% capacity decay per cycle. Moreover, we have revealed that the introduction of K-CA controlled the chelating rate of Fe(II) and the addition of KCl increased the K+ content, hence improving the capacity and stability of the as -prepared electrodes. Structural evolution and potassium storage mechanism were further investigated by detailed ex-situ X-ray diffraction and in-situ Raman measurements, which demonstrated reversible potassiation/depotassiation behavior and negligible volume change during the electrochemical process. In general, this work provides an efficient strategy to eliminate water contents in Prussian blue cathode and improve its electrochemical performance, which plays a key role in promoting the industrialization of potassium ion batteries. (c) 2023 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by ELSEVIER B.V. and Science Press. All rights reserved.