Conductivity Enhancement of Fractured Carbonates through High- Temperature Diammonium Hydrogen Phosphate Consolidation: A Preliminary Study

In well stimulation operations, the ability to sustain long- term conductivity of hydraulic/acid fractures defines an efficient and effective hydrocarbon production operation. However, it is challenging to keep the fracture conductive in the soft and weak carbonate formations due to many challenges. For example, the plastic deformation of rocks causes proppant embedment or asperities failure, resulting in fracture conductivity reduction. Consolidating chemicals, particularly diammonium hydrogen phosphate (DAP), have shown to be effective in rock consolidation and could reduce the decline in fracture conductivity if applied to carbonate formations. The previous research tested DAP at ambient conditions, whereas this work involves studying the hardening properties of DAP at reservoir conditions. The solutions with two initial concentrations (1 and 0.8 M) were tested at 77 degrees F (ambient), 122 degrees F, and 176 degrees F. Furthermore, a post-treatment analysis was conducted to compare the performance of the chemical under different conditions. The analysis included understanding the changes in carbonate rocks' (limestone and chalk) hardness (impulse hammer test and indenta-tion test), porosity (helium porosimeter), permeability (steady -state and unsteady state nitrogen injection), and mineralogy [X- ray diffraction (XRD) and scanning electron microscopy (SEM)]. Results demonstrated that both rock lithologies reacted efficiently with the DAP solution, presented in terms of the noticeable improvements in their hardness. The elevated temperatures positively affected rock hardness, leading to a more than 100% increase in hardness for most samples. After obtaining successful results from experiments at various temperatures, the pilot American Petroleum Institute (API) conductivity experiments were conducted, testing the conductivity sustenance through the rock hardening concept. Preliminary API conductivity experiments have demonstrated that treated rock samples with DAP provided higher conductivity values than the untreated samples at high stresses. The results shown in this study provide a good foundation for further studies on the implementation of DAP in actual acid/hydraulic fracturing field operations.