Spectroscopic and structural studies on phenyl and pentafluorophenyl trifluorothioacetate, and pentafluorophenyl trifluoroacetate, CF₃C(O)SC₆H₅, CF₃C(O)SC₆F₅ and CF₃C(O)OC₆F₅

Vanina M. Cayón,Mauricio F. Erben,Rosana M. Romano,Hans-Georg Stammler,Norbert W. Mitzel,Carlos O. Della Védova

Physical Chemistry Chemical Physics（2023）

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摘要

The new CF3C(O)SC6F5 and the already known CF3C(O)SC6H5, and CF3C(O)OC6F5 species were studied using a set of techniques and spectroscopies thus confirming the syn conformational transferability for these kind of oxo- and thioester compounds.

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关键词

pentafluorophenyl trifluorothioacetate,pentafluorophenyl trifluoroacetate,spectroscopic

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Spectroscopic and structural studies on phenyl and pentafluorophenyl trifluorothioacetate, and pentafluorophenyl trifluoroacetate, CF3C(O)SC6H5, CF3C(O)SC6F5 and CF3C(O)OC6F5

Spectroscopic and structural studies on phenyl and pentafluorophenyl trifluorothioacetate, and pentafluorophenyl trifluoroacetate, CF₃C(O)SC₆H₅, CF₃C(O)SC₆F₅ and CF₃C(O)OC₆F₅