Synthesis of RuO2/h-Co3O4 Electrocatalysts Derived from Hollow ZIF and Their Applications for Oxygen Evolution Reaction

APPLIED CHEMISTRY FOR ENGINEERING(2023)

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摘要
To improve the efficiency of water electrolysis, it is essential to develop an oxygen evolution reaction (OER) electrocatalyst with high performance and long-term stability, accelerating the reaction rate of OER. In this study, a hollow metal-organic framework (MOF)-derived ruthenium-cobalt oxide catalyst was developed to synthesize an efficient OER electrocatalyst. As the synthesized catalyst increases the surface exposure of ruthenium, a low overpotential (386 mV) was observed at a current density of 10 mA/cm2 with a low Tafel slope. It is expected to be able to replace noble metal catalysts by showing higher mass activity and stability than commercial RuO2 catalysts.
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关键词
Hollow structure, Metal-organic frameworks, Zelolitic imidazolate framwork, Water splitting, Oxygen evolution reaction
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