CThe Dynamic Interaction of Surfactants with Colloidal Molybdenum Disulfide Nanosheets Calls for Thermodynamic Stabilization by Solvents

Top-down liquid-phase exfoliation (LPE) and bottom-up hot-injection synthesis are scalable methods to produce Generally thought off as two entirely different fields, we show that similar stabilization mechanisms apply to colloids of molybdenum disulfide (MoS2) produced by both methods. By screening the colloidal stability of MoS2 produced in a hot-injection synthesis in a wide range of solvents, we observe that colloidal stability can be understood based on solution thermodynamics, wherein matching the solubility parameter of solvent and nanomaterial maximizes colloidal stability. Identical to MoS2 produced through LPE, optimal solvents to disperse MoS2 produced from the bottom-up have similar solubility parameters of approximate to 22 MPa1/2 and include aromatic solvents with polar functionalities, such as o-dichlorobenzene, and polar aprotic solvents, such as N,N-dimethylformamide. We further complemented our findings by nuclear magnetic resonance (NMR) spectrscopy, highlighting that organic surfactants, such as oleylamine and oleic acid, have a minimal affinity toward the nanocrystal surface and engage in a highly dynamic adsorption/desorption equilibrium. We thus conclude that hot injection yields MoS2 colloids with comparable surfaces as those produced by LPE. These similarities might offer the prospect of using established procedures developed for LPE nanomaterials to postprocess colloidally synthesized dispersions of 2D colloids as processable inks.