Unraveling Optical and Electrical Gains of Perovskite Solar Cells with an Antireflective and Energetic Cascade Electron Transport Layer.

Electron transport layers (ETLs) are imperative in n-i-p structured perovskite solar cells (PSCs) because of their capability to affect light propagation, electron extraction, and perovskite crystallization, and any mismatch of optical constants, band position, and surface potential between the ETLs and the perovskites can cause unintentional optical and electrical losses. Herein, an antireflective and energetic cascade bilayer ETL with ubiquitously used SnO and TiO was constructed at 150 °C for PSCs, and the in-depth mechanism for performance improvement was systematically unraveled. It was revealed that the construction of an ETL with gradually increasing refractive indices can circumvent light reflection loss, resulting in enhanced photocurrent. The combined ETL forms an energetic cascade to promote electronic conductivity and facilitate electron extraction with reduced energy loss. Moreover, topologic perovskite growth with improved crystallinity and vertical orientation was preferred owing to the relative dewetting behavior, leading to reduced defect states and enhanced carrier mobility in the perovskite layer.