Aggregation-induced circularly polarized phosphorescence of Pt(II) complexes with an axially chiral BINOL ligand.

Daiki Tauchi, Taiki Koida,Yuki Nojima,Masahi Hasegawa,Yasuhiro Mazaki,Akiko Inagaki,Ken-Ichi Sugiura,Yuki Nagaya,Kazunori Tsubaki,Takuya Shiga,Yuuya Nagata,Hiroyuki Nishikawa

Chemical communications (Cambridge, England)（2023）

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摘要

A pair of chiral Pt(II) complexes coordinated by simple BINOL and bipyridine ligands displaying aggregation-induced phosphorescence and circularly polarized luminescence were characterized by X-ray crystallography and absorption and emission spectroscopies. The emission of the powder sample was reddish whereas the thin film dispersed in PMMA ( = 1 wt%) exhibited a white emission.

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