Collective excitations in a melt of fast phase change material GeCu 2 Te 3 .

Journal of physics. Condensed matter : an Institute of Physics journal(2023)

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摘要
Inelastic x-ray scattering measurements have been carried out to investigate atomic dynamics in a melt of fast phase change material GeCuTe. The dynamic structure factor was analysed using the model function with three damped harmonic oscillator components. By investigating the correlation between the excitation energy and the linewidth, and that between the excitation energy and the intensity on contour maps of a relative approximate probability distribution function proportional toexp(-χ2/N), we could judge the reliability of each inelastic excitation in the dynamic structure factor. The results indicate that there are two inelastic excitation modes besides the longitudinal acoustic one in the liquid. The lower energy excitation could be assigned to the transverse acoustic one whereas the higher energy one disperses like fast sound. The latter result may imply that the liquid ternary alloy exhibits a microscopic phase separation tendency.
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关键词
atomic dynamics,fast phase change material,fast sound,inelastic x-ray scattering,liquid GeCu2Te3,transverse acoustic mode
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