Experimental and theoretical insight into biphasic extractive mass transfer of thorium into ionic liquid phase using chloroamide ligands

Shraddha Deshmukh,Aditya Madan Bhatt,Anil Boda,Rohit Singh Chauhan,Sk. Musharaf Ali,Arijit Sengupta

Journal of Molecular Liquids（2023）

引用 2|浏览14

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摘要

•Biphasic mass transfer using 'cation exchange' mechanism ML3 complex.•Slower kinetics, spontaneous and endothermic mass transfer.•Two types of Th-O bond (Th-OnitrateL1 ∼ 2.511A˚, Th-OligandL1 ∼ 2.411A˚ and Th-OnitrateL2 ∼ 2.518A˚, Th-OligandL2 ∼ 2.422A˚)•Gibb's energy from DFT followed the trend: ΔGgasphase > ΔGionicliquid and ΔGL1 > ΔGL2.

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关键词

Thorium,Cation exchange mechanism,Ionic liquid,Endothermic,DFT

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