Methods and benefits of measuring non-hydrocarbon gases from surface casing vents

Surface casing vents divert natural gas migration along oil and gas boreholes to bypass groundwater, with the gas venting to the atmosphere. While this strategy is designed to protect groundwater, it constitutes a source of greenhouse gases to the atmosphere. In instances where gas leakage occurs, the characterization of the molecular and isotopic composition of natural gas emitted from surface casing vent flows can be used to assist in identifying the gas source. We compare concentration measurements of non-hydrocarbon gases (within natural gas) of samples analyzed by laboratory-based gas chromatography (N 2 , Ar, CO 2 and O 2 ) and magnetic sector noble gas mass spectrometry (He, Ar and Kr) with field measurements conducted using a field portable quadrupole mass spectrometer (miniRUEDI). The standard deviation of miniRUEDI concentration results was within plus/minus one standard deviation of samples measured using laboratory-based GC (N 2 , O 2 , Ar and He) and magnetic sector noble gas mass spectrometry (He, Ar). Additional laboratory-based determination of isotope ratios of methane and argon (δ 13 C CH4 , δ 2 H CH4 , and 40 Ar/ 36 Ar) enabled a comparison between information provided by the analysis of reactive gases compared with noble gas isotopes. Gases from different sources displayed quantifiable differences in δ 13 C CH4 and δ 2 H CH4 , but these changes may or may not be distinguished if only one sampling event is conducted. By comparison, 40 Ar/ 36 Ar further enabled the differentiation of various gas sources. The objective of this paper is to discuss the advantages and trade-offs of the three different analysis methods considered, and the feasibility of their application in different environmental monitoring scenarios.