Framework robustness in early d-block metal complexes with tripodal polyalcohol ligands

Carla Krupczak,Bruno J. Stoeberl,Kátia C.M. Westrup,Lorenzo Tesi,Francielli S. Santana,Siddhartha O.K. Giese,Fabiano Yokaichiya,Daniel da S. Costa,Juliana M. Missina,Danilo Stinghen,David L. Hughes,Roberta Sessoli,Giovana G. Nunes,Dayane M. Reis,Jaísa F. Soares

Journal of Molecular Structure（2023）

引用 0|浏览15

暂无评分

摘要

•Tripodal alcohols provide versatile coordination modes for transition metal ions.•Spontaneous polyalcohol deprotonation leads to binuclear MIII complexes.•The versatile tripodal ligands confer notable robustness to the binuclear aggregates.•Products are formed in air or inert atmosphere and non-protic or protic media.•Metal ion oxidation or solvent loss does not lead to product decomposition.

查看译文

关键词

Binuclear,Tripodal,Polyalcohol,Spontaneous deprotonation,Early transition metal,Intermolecular interactions

AI 理解论文

溯源树

样例

生成溯源树，研究论文发展脉络

Chat Paper

正在生成论文摘要