Self-compensating geopolymer utilizing nano-clay and chopped basalt fibers

Construction and Building Materials(2022)

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摘要
To eliminate the drying shrinkage as well as improve toughness of alkali activated geopolymer, the nano-sized laponite and chopped basalt fibers were utilized as additives to prepare self-compensating reinforced geo-polymer. The magnesium-silicate laponite featured with gelable properties was found to influence geo-polymerization in the slag/fly ash-based alkali system. This was validated by the new formation of hydration products as hydrotalcite-like phase (Ht). The release of Mg2+ under activation promoted the participation of Al from the starting materials (slag and fly ash). Near-zero shrinkage was obtained at the dosage of laponite 4.0-5.0 wt% in the slag/fly ash-based geopolymetric mortars. The composite mortars exhibited excellent tensile-bond strength up to 5.7 MPa, and the low numbers pores of per unit area was achieved compared to other literatures. The flexural strength was improved by 51 % when the geopolymer was incorporated with flexible basalt fibers as modified with polyvinyl alcohol at dosage of 4.0 vol%.
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关键词
Self-compensating,Composite Geopolymer,Shrinkage,Basalt fiber,Laponite,Hydrotalcite-like phase
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