Biomimetic Porous MXene Sediment-Based Hydrogel for High-Performance and Multifunctional Electromagnetic Interference Shielding.

Developing high-performance and functional hydrogels that mimic biological materials in nature is promising yet remains highly challenging. Through a facile, scalable unidirectional freezing followed by a salting-out approach, a type of hydrogels composed of "trashed" MXene sediment (MS) and biomimetic pores is manufactured. By integrating the honeycomb-like ordered porous structure, highly conductive MS, and water, the electromagnetic interference (EMI) shielding effectiveness is up to 90 dB in the X band and can reach more than 40 dB in the ultrabroadband gigahertz band (8.2-40 GHz) for the highly flexible hydrogel, outperforming previously reported porous EMI shields. Moreover, thanks to the stable framework of the MS-based hydrogel, the influences of water on shielding performance are quantitatively identified. Furthermore, the extremely low content of silver nanowire is embedded into the biomimetic hydrogels, leading to the significantly improved multiple reflection-induced microwave loss and thus EMI shielding performance. Last, the MS-based hydrogels allow sensitive and reliable detection of human motions and smart coding. This work thus not only achieves the control of EMI shielding performance via the interior porous structure of hydrogels, but also demonstrates a waste-free, low-cost, and scalable strategy to prepare multifunctional, high-performance MS-based biomimetic hydrogels.