Copper-promoted C1−H amination of pyrrolo[1,2-a]quinoxaline with N‑fluorobenzenesulfonimide

Di Hao,Zhen Yang,Yali Liu,Yang Li,Yan Liu,Ping Liu

Journal of Molecular Structure（2022）

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摘要

•A copper-promoted direct C1-amination of pyrrolo[1,2-a]quinoxalines with N-fluorobenzenesulfonimide (NFSI) has been achieved.•A series of C1-aminated pyrrolo[1,2-a]quinoxalines were obtained with broad substrate scope.•Gram-scale synthesis and further derivation of this aminated product were also investigated.

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关键词

Pyrrolo[1,2-a]quinoxaline,N‑fluorobenzenesulfonimide,C−H amination

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