Mercury and REE contents in fruticose lichens from volcanic areas of the south volcanic zone

Volcanic eruptions represent one of the natural sources of Hg along with evasion from the oceans. This work evaluates the influence of these sources on the Hg bioaccumulation by fruticose lichens. The sampling areas were located in nearby sites affected by recent volcanic activity in the Patagonia Andean range. Geological techniques such as the study of REE and multi-element patterns were used to identify the volcanic ash sources. The relationship among Hg and semi volatile elements with the distance to the emitting points were considered. In general, the results found in the lichens were in agreement with the provenance of glass fractions from volcanic eruptions in the influenced zone. The diagrams of lichen multi-elements concentration showed similar patterns for lichens taken from locations further south (near Hudson volcano) which were different from the lichens taken from the northern area (near Puyehue, Calbuco and Copahue volcanoes). The average values of LREE/MREE showed similar values in lichen samples taken from the north and south areas from Puyehue Cordon Caulle Volcanic Complex and the ranges of the volcanic glass particles expelled during the 2011 eruption. The results suggest that normalized patterns of the REEs in fruticose lichens might provide a proxy record of the elements released from a volcanic source. Correlations of concentration of semi volatile elements to the volcanic distances and to the Pacific Ocean showed that Hg and Sb bioaccumulation in lichens had one or both contributions.