Direct conversion of almond waste into value-added liquids using carbon-neutral catalysts: Hydrothermal hydrogenation of almond hulls over a Ru/CNF catalyst

The almond industry leaves behind substantial amounts of by-products, with almond hulls being the primary residue generated. Given that one way to improve food security is by decreasing waste to reduce environmental impacts, developing sustainable processes to manage this by-product is necessary. Herein, we report on the hydrothermal hydrogenation of almond hulls over a carbon-neutral Ru supported on carbon nanofibres (Ru/CNF) catalyst, addressing the temperature, H2 pressure, time and catalyst loading. These variables controlled the distribution of the reaction products: gas (0–5%), liquid (49–82%) and solid (13–51%), and ruled the composition of the liquid effluent. This aqueous fraction comprised oligomers (46–81 wt%), saccharides (2–7 wt%), sugar alcohols (2–15 wt%), polyhydric alcohols (1–8 wt%) and carboxylic acids (7–31 wt%). The temperature and reaction time influenced the extension of hydrolysis, depolymerisation, deamination, hydrolysis, hydrogenation and dehydration reactions. Additionally, the initial H2 pressure and catalyst loading kinetically promoted these transformations, whose extensions were ruled by the amount of H2 effectively dissolved in the reaction medium and the prevalence of hydrogenations over dehydration/decarboxylation reactions or vice versa depending on the catalyst loading.