Scalable semitransparent prototype organic photovoltaic module with minimal resistance loss

Organic Electronics(2021)

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摘要
Semi-transparent organic photovoltaic (ST-OPV) cells are regarded as an attractive solution to building-integrated solar energy harvesting. Both the power conversion efficiency (PCE) and average photopic transmission (APT) of ST-OPVs have shown substantial increases in recent years. However, less attention has been paid to the area scaling of ST-OPV cells. In this work, we investigate the scalability of ST-OPV cells from 4 mm2 to 1 cm2, as well as 9 cm2 active area prototype module. By integrating both top and bottom metal grids onto the transparent electrodes, the series resistance loss of 1 cm2 ST-OPV cell is significantly reduced, and is comparable to that of the grid-free 4 mm2 cell. Nine 1 cm2 cells are then connected in a series-parallel circuit to realize a prototype ST-OPV module. A 100% fabrication yield with only 5% PCE deviation among discrete cells is achieved. The semitransparent module shows PCE = 7.2 ± 0.1% under simulated AM 1.5G illumination at 1 sun intensity, which exhibits no connection resistance loss compared to that of the individual cells. The ST-OPV module exhibits an APT = 38.1 ± 1.1%, which enables a light utilization efficiency, LUE = 2.74 ± 0.09%. The method demonstrates a promising way for ST-OPV modules to scale without compromising performance.
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关键词
Solar cell,Module,Semitransparent,Nonfullerene acceptor
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