Hemi-metallocene Ti(IV) η3-allyl-type complexes: Structure, dynamics in solution and exploration of reactivity

Francesco Zaccaria,Cristiano Zuccaccia,Alceo Macchioni

Inorganica Chimica Acta（2021）

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摘要

•Cp*-phosphinimide Ti(IV)-(η3-allyl) complexes are highly stable at room temperature.•They exhibit a dynamic behavior in solution involving exchange of allylic protons.•They are able to allylate a typical carbonyl compound like benzaldehyde.

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关键词

Allyl complexes,Titanium,Exchange spectroscopy,Phosphinimide ligands,Chain transfer to monomer

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