Generation and Reactivity of a One-Electron-Oxidized Manganese(V) Imido Complex with a Tetraamido Macrocyclic Ligand.

Huatian Shi, Jianhui Xie Xie,William W. Y. Lam,Wai‐Lun Man,Chi‐Keung Mak,Shek‐Man Yiu,Hung Kay Lee,Tai‐Chu Lau

user-5da93e5d530c70bec9508e2b（2019）

引用 14|浏览3

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摘要

The synthesis and X-ray structure of a new manganese(V) mesitylimido complex with a tetraamido macrocyclic ligand (TAML), [MnV (TAML)(N-Mes)]- (1), are reported. Compound 1 is oxidized by [(p-BrC6 H4 )3 N]+. [SbCl6 ]- and the resulting MnVI species readily undergoes H-atom transfer and nitrene transfer reactions.

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关键词

Macrocyclic ligand,Nitrene,Reactivity (chemistry),Coordination complex,Manganese,Polymer chemistry,Chemistry,Electron

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