Liquid-Liquid Phase Separation In An Inhomogeneous Ternary Colloid-Polymer Mixture

Suspended colloids are often considered as models for molecules, which are sufficiently big so that they can be observed directly in (light) microscopes and for which the effective interaction among each other can be tailored. The Asakura-Oosawa model of ideal colloid-polymer mixtures captures the idea of tuning the interaction between the colloids via a potential, which possesses a range set by the size of the polymers and an attractive strength characterized by the (reservoir) number density of the polymers, which plays the role of an inverse temperature. The celebrated Asakura-Oosawa depletion potential allows one to recreate the bulk phase diagram of a simple fluid by employing a colloid-polymer mixture. This has been verified in theory, by computer simulations, and via experiments. Here, we study the phase behavior of a confined colloid-polymer mixture with two polymer species. The sizes and densities are chosen such that the resulting bulk phase diagram exhibits a second stable critical point within the framework of the classical density functional theory. Our results suggest that a suitably tuned colloid-polymer mixture can be an interesting model system to study fluids with two critical points.