Touch Sensor And Photovoltaic Characteristics Of Cusbs2 Thin Films

Spin-coated chalcostibite CuSbS2 thin films (approximate to 500 nm thick) were fabricated and the influence of the drying temperature on the structural, morphological, optical and thermoelectric properties of the films was investigated. Crystalline phase-pure chalcostibite has been obtained for the films dried at 180 degrees C and 210 degrees C, while below 180 degrees C these films are partially amorphous. Surprisingly, at drying temperature of 240 degrees C, a CuxS secondary phase appeared. The increase of the drying temperature leads to the increase of the particle size and the decrease of the optical band gap, which is interesting for optoelectronic applications. The highest power factor value was achieved for the film dried at 210 degrees C, due to the inexistence of secondary phases, which allowed realizing a stable thermoelectric touch sensor with a V-signal/noise of 5. In addition, this film was tested as a photovoltaic (PV) device and a power conversion efficiency (PCE) of 0.030% with an open-circuit voltage (V-OC) of 0.36 V, a short-circuit current density (J(SC)) of 0.278 mAcm(-2) and a fill factor (FF) of 0.27 were obtained. Therefore, this work evidences a pathway toward developing bi-functional devices with simultaneously thermoelectric touch sensor and photovoltaic functions.