Pivotal Reactions in the Creation of the Polycyclic Skeleton of Cryptotrione
Synlett(2021)
摘要
Three pivotal reactions, namely, enyne cycloisomerization, polyene cyclization, and quinone methide formation, are applied to synthesize the complex polycyclic skeleton of cryptotrione. This review summarizes the most prominent applications of these three reactions to the total syntheses of natural products, covering results published in the literature between 2011 and 2020.
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关键词
total synthesis,natural products,enyne cycloisomerization,polyene cyclization,quinone methides
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