The benzhydryl-modified 2-imino-1,10-phenanthrolyliron precatalyst in ethylene oligomerization

Jingjing Guo,Qiang Chen,Wenjuan Zhang,Tongling Liang,Wen-Hua Sun

Journal of Organometallic Chemistry（2021）

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摘要

•Ethylene oligomerization with 2-imino-1,10-phenanthrolyliron precatalyst.•Significant difference in ethylene oligomerization by complexes with mono- or bis-ortho-benzhydryls of N-Aryl group.•Ethylene dimerization by precatalysts with bis-ortho-benzhydryls of N-Aryl group.•Ethylene oligomerization by precatalysts with mono-ortho-benzhydryls of N-Aryl group.

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关键词

2-Imino-1,10-phenanthroline,Iron complex,Bulky influence of benzhydryl-substituent,Ethylene oligomerization

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