Thermal stability study of HFO-1234ze(E) for supercritical organic Rankine cycle: Chemical kinetic model approach through decomposition experiments

Journal of Industrial and Engineering Chemistry(2020)

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摘要
•Thermal stability evaluation of a new working fluid, HFO-1234ze(E), for SORC.•Simplified chemical kinetic model to predict the thermal stability of working fluid.•The activation energy of the decomposition was 113.33kJmol−1.•At the end of 50-year continuous cycle, 1.25% HFO-1234ze(E) will be decomposed.
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关键词
Supercritical organic Rankine cycle,Working fluid,HFO-1234ze(E),Decomposition,Kinetics
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