Polymerization of glycidyl methacrylate from the surface of cellulose nanocrystals for the elaboration of PLA-based nanocomposites.

Manon Le Gars,Julien Bras,Hanène Salmi-Mani,Marisol Ji,Diana Dragoe,Hajar Faraj,Sandra Domenek,Naceur Belgacem,Philippe Roger

Carbohydrate Polymers（2020）

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摘要

•Controlled polymerization at the surface of activated cellulose nanocrystals.•High coverages are obtained : 40 up to 80 % in weight percentage of relative to CNCs.•Cellulose nanocrystals dispersion inversely related to the grafted polymer amount.•Improvement of the interface between polymerized CNCs and poly(lactic acid) (PLA) matrix.

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关键词

Cellulose nanocrystals,Chemical grafting,Surface-initiated atom transfer radical polymerization,Poly(glycidyl methacrylate),Poly(lactic acid)-based nanocomposites,Compatibilization

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