Stereoselective synthesis of ( )-centrolobine
Tetrahedron: Asymmetry（2014）
摘要
The stereoselective synthesis of (−)-centrolobine has been accomplished starting from d-glyceraldehyde acetonide by a combination of chelation-controlled diastereoselective alkylation and ring-closing metathesis. A high degree of 1,3-asymmetric induction has been realized in an ether system.
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