Comparison of Pt-BaO/Al2O3 and Pt-CeO2/Al2O3 for NOx storage and reduction: Impact of cycling frequency

Applied Catalysis B: Environmental(2019)

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摘要
•NOx storage functionality is essential for lean NOx reduction with lean/rich cycling.•Ceria redox pathway only has a secondary effect on NOx conversion under excess O2.•Promotion by fast cycling is due to better usage of NOx and oxygen storage sites.•Excess O2 enhances or inhibits NOx reduction on Pt/CeO2/Al2O3 below or above 400 °C.•C3H6 enhances NOx reduction on Pt/CeO2/Al2O3 in stoichiometric case with fast cycling.
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关键词
NOx storage and reduction,Ceria,Platinum,Barium,Oxygen storage capacity
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