Facile and efficient Cu(0)-mediated radical polymerisation of pentafluorophenyl methacrylate grafting from poly(ethylene terephthalate) film

Thi Phuong Thu Nguyen,Nadine Barroca-Aubry,Diana Dragoe,Sandra Mazerat,François Brisset,Jean-Marie Herry,Philippe Roger

European Polymer Journal（2019）

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摘要

•PFPMA polymer was grafted from PET films via Cu(0)-mediated radical polymerisation.•The proposed surface-initiated polymerisation is robust yet handy to perform.•Grafted polymer fully covered supporting surfaces in both small and large scale setups.•Obtained surfaces showed enhancements in hydrophobicity, roughness and reactivity.

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关键词

Pentafluorophenyl methacrylate,Active ester,Poly(ethylene terephthalate),Surface-initiated polymerisation,Copper mediated polymerisation,Surface modification

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