New ligands for uranium complexation: A stable uranyl dimer bearing 2,6-diacetylpyridine dioxime

Inorganic Chemistry Communications(2017)

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摘要
The synthesis, characterization, and stability study of the first uranium complex bearing 2,6-diacetylpyridine dioxime (dapdoH2) is reported. The dimeric complex [UO2(dapdoH)Cl]2 is stable in solution as shown by ESI-MS and NMR spectrometry, and its solid-state structure was further analyzed by X-ray crystallography, IR, Raman and luminescence studies.
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关键词
2,6-Diacetylpyridine dioxime,Dinuclear complexes,Physical characterization,Spectroscopic characterization,Uranyl complexes
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