Ultrafast Ligand Self-Exchanging Gadolinium Complexes In Ionic Liquids For Nmr Field Probes
INORGANIC CHEMISTRY(2018)
摘要
Concurrent magnetic field monitoring in MRI with an array of NMR field probes allows for reducing image imperfections. High F-19 concentrations together with short relaxation times are basic probe properties. We present the NMR properties of [Gd(NTf2)(4)](-) dissolved in an ionic liquid consisting of an imidazolium cation and the [NTf2](-) anion. These solutions achieve fluorine concentrations as high as 26 M and rapid relaxation times in the sub-ms time range. The second order self-exchange rate of coordinated [NTf2](-) with [NTf2](-) as determined with [Y(NTf2)(4)](-) is 4.5 X 10(5).M-1.s(-1). X-ray structure analyses confirm the coordination number of eight around Gd(3+)and Y3+. These ionic-liquid solutions are thus excellent candidates for dynamically probing the NMR fields in MRI.
更多查看译文
AI 理解论文
溯源树
样例
生成溯源树,研究论文发展脉络
Chat Paper
正在生成论文摘要