Photoinduced Optical Functionalism of Branched Azophenylcarbazoles in Molecular Glass Matrices
MOLECULAR CRYSTALS AND LIQUID CRYSTALS(2012)
摘要
A new guest-host composition of 3-(4-nitrophenyl) azo-9-(2-ethyl) hexyl-2-(2-ethyl) hexyloxycarbazole as chromophore and 2,2-bis{4-[2-hydroxy-9-(carbazol-9-yl)-5-(carbazol-9-methyl)-4,7-dioxanonyloxy] phenyl} propane (molecular glass) as host for all-optical poling application was developed and investigated. A comparison between molecular glass and commonly used bisphenol Z polycarbonate as host showed a slightly better ability for the molecular glass to keep the azophenylcarbazole molecules oriented. Erasure while reading the non-centrosymmetry created is demonstrated and explained. Using an adopted model orientational diffusion coefficient, lifetime of cis isomer and probabilities of redistribution were evaluated.
更多查看译文
关键词
diffusion coefficient
AI 理解论文
溯源树
样例
生成溯源树,研究论文发展脉络
Chat Paper
正在生成论文摘要