Shear Propagation In The Terahertz Dynamics Of Water-Glycerol Mixtures

JOURNAL OF CHEMICAL PHYSICS(2013)

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摘要
Inelastic X-ray and neutron scattering techniques were jointly used to investigate the dynamics of water-glycerol mixtures at different concentrations and temperatures. It was observed that even relatively low concentrations of glycerol increase the damping of shear modes, as a consequence of the known ability of glycerol to disrupt the hydrogen bond network of water. A similar trend was observed when increasing the temperature, which suggests the presence of a locus in the concentration-temperature plane marking a crossover in the shear modulus. (C) 2013 AIP Publishing LLC.
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