Substitution effect on the regioselective halogen/metal exchange of 3-substituted 1,2,5-tribromobenzenes

Karsten Menzel,Paul M. Mills,Doug E. Frantz,Todd D. Nelson,Michael H. Kress

Tetrahedron Letters（2008）

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摘要

Regioselective halogen/metal exchange reactions using isopropylmagnesium chloride were studied on 3-substituted 1,2,5-tribromoarenes. Seven examples are given.

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关键词

1,2-Dibromobenzene,Grignard reactions,Halogen/metal exchange,Regioselectivity,Carboxylic acids

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