Physical properties of very thin SnS films deposited by thermal evaporation

SnS films with thicknesses of 20–65nm have been deposited on glass substrates by thermal evaporation. The physical properties of the films were investigated using X-ray diffraction (XRD), scanning electron microscopy, X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, and ultraviolet–visible-near infrared spectroscopy at room temperature. The results from XRD, XPS and Raman spectroscopy analyses indicate that the deposited films mainly exhibit SnS phase, but they may contain a tiny amount of Sn2S3. The deposited SnS films are pinhole free, smooth and strongly adherent to the surfaces of the substrates. The color of the SnS films changes from pale yellow to brown with the increase of the film thickness from 20nm to 65nm. The very smooth surfaces of the thin films result in their high reflectance. The direct bandgap of the films is between 2.15eV and 2.28eV which is much larger than 1.3eV of bulk SnS, this is deserving to be investigated further.