ChemInform Abstract: Synthesis of 2-Perfluoroalkyl-Substituted Acetals from the One-Pot Reaction of Perfluoroalkyl Iodides with Vinyl Ether and Alcoholates.

S. ZHU, C. QING, C. ZHOU,J. ZHANG, B. XU

Cheminform（2010）

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摘要

Abstract Treatment of perfluoroalkyl iodides, R f I (R f =C 4 F 9 , ClC 4 F 8 ), with alcoholales and vinyl ethyl ether gave 2-perfluoroalkyl acetals via perfluoroalkyl radical intermediates. Both R f and R f CH 2 CHOEt radicals were detected by ESR spectroscopy. A single-electron-transfer mechanism is proposed for this reaction.

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关键词

2-perfluoroalkyl-substituted iodides,acetals,vinyl ether,synthesis,one-pot

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